<?xml version="1.0" encoding="UTF-8"?><eml:eml xmlns:eml="https://eml.ecoinformatics.org/eml-2.2.0" xmlns:stmml="http://www.xml-cml.org/schema/stmml-1.1" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="https://eml.ecoinformatics.org/eml-2.2.0 https://lter.kbs.msu.edu/docs/eml-2.2.0/eml.xsd" packageId="knb-lter-kbs.71.67" system="KBS LTER"><access scope="document" order="allowFirst" authSystem="knb"><allow><principal>uid=KBS,o=lter,dc=ecoinformatics,dc=org</principal><permission>all</permission></allow><allow><principal>uid=sbohm,o=lter,dc=ecoinformatics,dc=org</principal><permission>all</permission></allow><allow><principal>public</principal><permission>read</permission></allow></access><dataset><alternateIdentifier system="lter.kbs.msu.edu">https://lter.kbs.msu.edu/datasets/71.eml</alternateIdentifier><title>Agronomic Soil Chemistry at the Kellogg Biological Station, Hickory Corners, MI  (1992 to 2025)</title><creator><individualName><givenName>Nicholas</givenName><surName>Haddad</surName></individualName><organizationName>Michigan State University</organizationName><address><deliveryPoint>3700 E Gull Lake Drive</deliveryPoint><city>Hickory Corners</city><postalCode>49060</postalCode><country>US</country></address><phone phonetype="phone"></phone><phone phonetype="fax"></phone><electronicMailAddress>haddad@kbs.msu.edu</electronicMailAddress><userId directory="http://orcid.org">0000-0002-1591-9322</userId></creator><creator><individualName><givenName>Joseph</givenName><surName>Simmons</surName></individualName><organizationName>Michigan State University</organizationName><address><deliveryPoint>3700 East Gull Lake Drive</deliveryPoint><city>Hickory Corners</city><administrativeArea>MI</administrativeArea><postalCode>49060</postalCode></address><phone phonetype="phone">(269) 671-2528</phone><phone phonetype="fax">(269)671-2104</phone><electronicMailAddress>simmonsj@kbs.msu.edu</electronicMailAddress></creator><associatedParty><individualName><givenName>G.</givenName><surName>Robertson</surName></individualName><organizationName>Michigan State University</organizationName><address><deliveryPoint>3700 East Gull Lake Drive</deliveryPoint><city>Hickory Corners</city><administrativeArea>MI</administrativeArea><postalCode>49060</postalCode><country>US</country></address><phone phonetype="phone">(269) 760-8364</phone><phone phonetype="fax">(269)671-2351</phone><electronicMailAddress>robert30@msu.edu</electronicMailAddress><userId directory="http://orcid.org">0000-0001-9771-9895</userId><role>original investigator</role></associatedParty><associatedParty><individualName><givenName>Stacey</givenName><surName>VanderWulp</surName></individualName><organizationName>Michigan State University</organizationName><address><deliveryPoint>3700 East Gull Lake Drive</deliveryPoint><city>Hickory Corners</city><administrativeArea>MI</administrativeArea><postalCode>49060</postalCode><country>US</country></address><phone phonetype="phone">(269) 671-2339</phone><phone phonetype="fax">(269) 671-2333</phone><electronicMailAddress>vanderws@msu.edu</electronicMailAddress><role>principal contact</role></associatedParty><pubDate>2026-05-18</pubDate><abstract><section><title>Dataset Abstract</title><para></para><para>original data source http://lter.kbs.msu.edu/datasets/71</para></section></abstract><keywordSet><keyword keywordType="place">LTER</keyword><keyword keywordType="place">KBS</keyword><keyword keywordType="place">Kellogg Biological Station</keyword><keyword keywordType="place">Hickory Corners</keyword><keyword keywordType="place">Michigan</keyword><keyword keywordType="place">Great Lakes</keyword></keywordSet><keywordSet><keyword keywordType="theme">ph</keyword><keyword keywordType="theme">soil</keyword><keyword keywordType="theme">pH</keyword><keyword keywordType="theme">phosphorus</keyword><keyword keywordType="theme">chemistry</keyword><keyword keywordType="theme">cec</keyword><keyword keywordType="theme">potassium</keyword><keyword keywordType="theme">CEC</keyword></keywordSet><keywordSet><keyword>Inorganic Nutrients</keyword><keyword>Disturbance</keyword><keywordThesaurus>LTER Core Research Area</keywordThesaurus></keywordSet><keywordSet><keyword>cation exchange capacity cations pH nutrient phosphorous soil chemistry cec soil potassium CEC</keyword></keywordSet><keywordSet><keyword keywordType="theme">farming</keyword><keyword keywordType="theme">biota</keyword><keywordThesaurus>https://apps.usgs.gov/thesaurus/thesaurus-full.php?thcode=15</keywordThesaurus></keywordSet><intellectualRights><para>Data in the KBS LTER core database may not be published without written permission of the lead investigator or project director. These restrictions are intended mainly to preserve the primary investigators' rights to first publication and to ensure that data users are aware of the limitations that may be associated with any specific data set. These restrictions apply to both the baseline data set and to the data sets associated with specific LTER-supported subprojects.</para><para>All publications of KBS data and images must acknowledge KBS LTER support.</para></intellectualRights><coverage><geographicCoverage><geographicDescription>The areas around the Kellogg Biological Station in southwest Michigan</geographicDescription><boundingCoordinates><westBoundingCoordinate>-85.404699</westBoundingCoordinate><eastBoundingCoordinate>-85.366857</eastBoundingCoordinate><northBoundingCoordinate>42.420265</northBoundingCoordinate><southBoundingCoordinate>42.391019</southBoundingCoordinate></boundingCoordinates></geographicCoverage><temporalCoverage><rangeOfDates><beginDate><calendarDate>1992-11-24</calendarDate></beginDate><endDate><calendarDate>2023-12-08</calendarDate></endDate></rangeOfDates></temporalCoverage></coverage><contact><organizationName>Kellogg Biological Station</organizationName><positionName>Data Manager</positionName><electronicMailAddress>lter.data.manager@kbs.msu.edu</electronicMailAddress><onlineUrl>http://lter.kbs.msu.edu</onlineUrl><userId directory="https://ror.org/">02vkce854</userId></contact><publisher><organizationName>KBS LTER</organizationName></publisher><methods><methodStep><description>Surface (0-25 cm) soil samples are typically collected in the fall, composited by plot, and sent to an analytical laboratory for analysis and for nutrient and liming recommendations for field crops. Analyses include pH, lime index, phosphorus, potassium, calcium, magnesium, and cation exchange capacity. Samples collected in the fall provide liming and fertilizer recommendations for the following year.

Deep cores (0-100 cm) are collected every 5-10 years and samples are analyzed separately by depth interval to monitor longer-term changes in composition with depth.

Sampling frequency: Depends on experiment and research objective.
</description><protocol id="protocol_178"><title>Agronomic Soil Chemistry – Analytical Lab Analysis</title><creator><positionName>Data Manager</positionName></creator><distribution><online><url>http://lter.kbs.msu.edu/protocols/178</url></online></distribution></protocol></methodStep><methodStep><description>The LTER Nitrogen Deposition Study was established in 2001 to examine the effects of increased nitrogen deposition on successional and forested communities. Nitrogen fertilizer is applied annually at three different levels to plots adjacent to Mid-successional (SF), Coniferous Forest (CF) and Deciduous Forest (DF) treatments of the LTER Main Cropping System Experiment (MCSE). Since 2010*, these plots are preferentially fertilized with ammonium nitrate (NH4NO3)† at the following rates:

One-fold fertilization (1F) = 1 g Nitrogen (N) m-2 yr-1= 10 kg N ha-1 yr-1
Three-fold fertilization (3F) = 3 g N m-2 yr-1 = 30 kg N ha-1 yr-1
Ten-fold fertilization (10F in DF only) = 10 g N m-2 yr-1 = 100 kg N ha-1 yr-1

The 1F plots are 100 m2 (10m x 10 m) each, with the exception of CF3 which is 6 m2 (2m x 3 m). The annual application rate is 10 kg N ha-1 as an ammonium nitrate (NH4NO3)† solution, equivalent to 100 g (6 g on CF3) N per plot. N is applied in 3 doses of 3.33 kg N ha--1each diluted to 4 L (2 L on CF3). The three doses are evenly spaced from April through November (after spring thaw through litterfall) and are preferentially applied to all deposition plots on the same day.
The 3F plots are 4 m2 (2m x 2m) each. The annual application rate is 30 kg N ha-1 added in 3 doses of 10 kg N ha-1 each diluted to 2 L per plot.
The 10F plots were added to the DF treatment only in 2007 and are 4 m2 (2m x 2m) each. The annual application rate is 100 kg N ha-1 added in 3 doses of 2 L per plot.
See the Detailed Fertilization Log for specifics on fertilization dates and type of fertilizer applied.

</description><protocol id="protocol_121"><title>Nitrogen Deposition Study – Fertilizer Treatments</title><creator><positionName>Data Manager</positionName></creator><distribution><online><url>http://lter.kbs.msu.edu/protocols/121</url></online></distribution></protocol></methodStep></methods><project><title>LTER: KBS - Ecological and Social Mechanisms of Resilience in Agroecosystems</title><personnel><organizationName/><role>program</role></personnel><award><funderName>National Science Foundation</funderName><funderIdentifier>http://dx.doi.org/10.13039/100000001</funderIdentifier><awardNumber>DEB 2224712</awardNumber><title>LTER: KBS - Ecological and Social Mechanisms of Resilience in Agroecosystems</title><awardUrl>https%3A%2F%2Fnsf.gov%2Fawardsearch%2FshowAward%3FAWD_ID%3D2224712%26HistoricalAwards%3Dfalse</awardUrl></award></project><dataTable><alternateIdentifier system="lter.kbs.msu.edu">https://lter.kbs.msu.edu/datatables/52</alternateIdentifier><entityName>Kellogg Biological Station LTER: Agronomic Soil Chemistry (KBS066-001)</entityName><entityDescription>Soil chemistry of surface (0-25 cm) samples collected annually for MCSE Treatments 1-4 and 6 (since 1992), on a near annual basis for Treatments 5, 7 and 8, and less frequently for the unmanaged sites (TCF, TDF and TCF).</entityDescription><physical><objectName>Agronomic+Soil+Chemistry.csv</objectName><encodingMethod>None</encodingMethod><dataFormat><textFormat><numHeaderLines>39</numHeaderLines><numFooterLines>1</numFooterLines><recordDelimiter>\n</recordDelimiter><attributeOrientation>column</attributeOrientation><simpleDelimited><fieldDelimiter>,</fieldDelimiter><collapseDelimiters>no</collapseDelimiters><quoteCharacter>"</quoteCharacter><literalCharacter>\</literalCharacter></simpleDelimited></textFormat></dataFormat><distribution><online><url>https://lter.kbs.msu.edu/datatables/52.csv</url></online></distribution></physical><attributeList><attribute><attributeName>Sample_Date</attributeName><attributeDefinition>date the sample was taken on</attributeDefinition><measurementScale><dateTime><formatString>YYYY-MM-DD</formatString><dateTimePrecision>1</dateTimePrecision><dateTimeDomain><bounds><minimum exclusive="true">1987-4-18</minimum></bounds></dateTimeDomain></dateTime></measurementScale></attribute><attribute><attributeName>Treatment</attributeName><attributeDefinition>main site treatment</attributeDefinition><measurementScale><nominal><nonNumericDomain><textDomain><definition>main site treatment</definition></textDomain></nonNumericDomain></nominal></measurementScale></attribute><attribute><attributeName>Replicate</attributeName><attributeDefinition>main site replicate</attributeDefinition><measurementScale><nominal><nonNumericDomain><textDomain><definition>main site replicate</definition></textDomain></nonNumericDomain></nominal></measurementScale></attribute><attribute><attributeName>Depth</attributeName><attributeDefinition>sample depth</attributeDefinition><measurementScale><nominal><nonNumericDomain><textDomain><definition>sample depth</definition></textDomain></nonNumericDomain></nominal></measurementScale></attribute><attribute><attributeName>pH</attributeName><attributeDefinition>measured pH</attributeDefinition><measurementScale><nominal><nonNumericDomain><textDomain><definition>measured pH</definition></textDomain></nonNumericDomain></nominal></measurementScale></attribute><attribute><attributeName>CEC</attributeName><attributeDefinition>cation exchange capacity in meq/100g soil</attributeDefinition><measurementScale><ratio><unit><customUnit>milliEquivalentsPerHundredGram</customUnit></unit><numericDomain><numberType>real</numberType></numericDomain></ratio></measurementScale></attribute><attribute><attributeName>phosphorus</attributeName><attributeDefinition>Bray P1 phosphorus</attributeDefinition><measurementScale><ratio><unit><customUnit>milligramsPerGram</customUnit></unit><numericDomain><numberType>real</numberType></numericDomain></ratio></measurementScale></attribute><attribute><attributeName>potassium</attributeName><attributeDefinition>potassium</attributeDefinition><measurementScale><ratio><unit><customUnit>milligramsPerGram</customUnit></unit><numericDomain><numberType>real</numberType></numericDomain></ratio></measurementScale></attribute><attribute><attributeName>calcium</attributeName><attributeDefinition>calciium</attributeDefinition><measurementScale><ratio><unit><customUnit>milligramsPerGram</customUnit></unit><numericDomain><numberType>real</numberType></numericDomain></ratio></measurementScale></attribute><attribute><attributeName>magnesium</attributeName><attributeDefinition>magnesium</attributeDefinition><measurementScale><ratio><unit><customUnit>milligramsPerGram</customUnit></unit><numericDomain><numberType>real</numberType></numericDomain></ratio></measurementScale></attribute><attribute><attributeName>lime_index</attributeName><attributeDefinition>lime index</attributeDefinition><measurementScale><interval><unit><standardUnit>dimensionless</standardUnit></unit><numericDomain><numberType>real</numberType></numericDomain></interval></measurementScale></attribute><attribute><attributeName>zn_ppm</attributeName><attributeDefinition>zinc</attributeDefinition><measurementScale><ratio><unit><customUnit>milligramsPerGram</customUnit></unit><numericDomain><numberType>real</numberType></numericDomain></ratio></measurementScale></attribute><attribute><attributeName>s_ppm</attributeName><attributeDefinition>sulfur</attributeDefinition><measurementScale><ratio><unit><customUnit>milligramsPerGram</customUnit></unit><numericDomain><numberType>real</numberType></numericDomain></ratio></measurementScale></attribute><attribute><attributeName>b_ppm</attributeName><attributeDefinition>boron</attributeDefinition><measurementScale><ratio><unit><customUnit>milligramsPerGram</customUnit></unit><numericDomain><numberType>real</numberType></numericDomain></ratio></measurementScale></attribute><attribute><attributeName>comment</attributeName><attributeDefinition>comment</attributeDefinition><measurementScale><nominal><nonNumericDomain><textDomain><definition>comment</definition></textDomain></nonNumericDomain></nominal></measurementScale></attribute><attribute><attributeName>year</attributeName><attributeDefinition>year of the sample</attributeDefinition><measurementScale><dateTime><formatString>YYYY</formatString><dateTimePrecision>1</dateTimePrecision><dateTimeDomain><bounds><minimum exclusive="true">1987-4-18</minimum></bounds></dateTimeDomain></dateTime></measurementScale></attribute><attribute><attributeName>top_depth_cm</attributeName><attributeDefinition>the top depth of the sample as measured from the soil surface</attributeDefinition><measurementScale><ratio><unit><standardUnit>centimeter</standardUnit></unit><numericDomain><numberType>real</numberType></numericDomain></ratio></measurementScale></attribute><attribute><attributeName>bottom_depth_cm</attributeName><attributeDefinition>the bottom depth of the sample as measured from the soil surface.</attributeDefinition><measurementScale><ratio><unit><standardUnit>centimeter</standardUnit></unit><numericDomain><numberType>real</numberType></numericDomain></ratio></measurementScale></attribute><attribute><attributeName>lab</attributeName><attributeDefinition>the lab that did the analysis</attributeDefinition><measurementScale><nominal><nonNumericDomain><textDomain><definition>the lab that did the analysis</definition></textDomain></nonNumericDomain></nominal></measurementScale></attribute><attribute><attributeName>duplicate</attributeName><attributeDefinition>duplicate sample sent to the lab to determine within sample consistency. 0 means that no duplicates were sent, a number greater than zero are a label for duplicate samples.</attributeDefinition><measurementScale><nominal><nonNumericDomain><textDomain><definition>duplicate sample sent to the lab to determine within sample consistency. 0 means that no duplicates were sent, a number greater than zero are a label for duplicate samples.</definition></textDomain></nonNumericDomain></nominal></measurementScale></attribute></attributeList></dataTable><dataTable><alternateIdentifier system="lter.kbs.msu.edu">https://lter.kbs.msu.edu/datatables/665</alternateIdentifier><entityName>Kellogg Biological Station LTER: Agronomic Soil Chemistry (KBS066-002)</entityName><entityDescription>Soil chemistry of surface (0-25 cm) samples occasionally collected from the nitrogen fertilized microplots (1F, 3F and 10F) of the Nitrogen Deposition Study located adjacent to the main plots of the MCSE Mid-successional (SF) and Coniferous (CF) and Deciduous (DF) forested sites. Note that the 0F nitrogen treatment refers to samples collected within the main plot, which is unfertilized.</entityDescription><physical><objectName>Agronomic+Soil+Chemistry.csv</objectName><encodingMethod>None</encodingMethod><dataFormat><textFormat><numHeaderLines>38</numHeaderLines><numFooterLines>1</numFooterLines><recordDelimiter>\n</recordDelimiter><attributeOrientation>column</attributeOrientation><simpleDelimited><fieldDelimiter>,</fieldDelimiter><collapseDelimiters>no</collapseDelimiters><quoteCharacter>"</quoteCharacter><literalCharacter>\</literalCharacter></simpleDelimited></textFormat></dataFormat><distribution><online><url>https://lter.kbs.msu.edu/datatables/665.csv</url></online></distribution></physical><attributeList><attribute><attributeName>sample_date</attributeName><attributeDefinition>date of sampling</attributeDefinition><measurementScale><dateTime><formatString>YYYY-MM-DD</formatString><dateTimePrecision>1</dateTimePrecision><dateTimeDomain><bounds><minimum exclusive="true">1987-4-18</minimum></bounds></dateTimeDomain></dateTime></measurementScale></attribute><attribute><attributeName>habitat</attributeName><attributeDefinition>sampling habitat</attributeDefinition><measurementScale><nominal><nonNumericDomain><textDomain><definition>sampling habitat</definition></textDomain></nonNumericDomain></nominal></measurementScale></attribute><attribute><attributeName>nitrogen_treatment</attributeName><attributeDefinition>nitrogen application treatment</attributeDefinition><measurementScale><nominal><nonNumericDomain><textDomain><definition>nitrogen application treatment</definition></textDomain></nonNumericDomain></nominal></measurementScale></attribute><attribute><attributeName>nitrogen_application_rate</attributeName><attributeDefinition>rate of N application</attributeDefinition><measurementScale><ratio><unit><standardUnit>gramsPerSquareMeter</standardUnit></unit><numericDomain><numberType>real</numberType></numericDomain></ratio></measurementScale></attribute><attribute><attributeName>depth</attributeName><attributeDefinition>soil sampling depth</attributeDefinition><measurementScale><interval><unit><standardUnit>centimeter</standardUnit></unit><numericDomain><numberType>text</numberType></numericDomain></interval></measurementScale></attribute><attribute><attributeName>cec</attributeName><attributeDefinition>cation exchange capacity in meq/100g soil</attributeDefinition><measurementScale><ratio><unit><customUnit>milliEquivalentsPerHundredGram</customUnit></unit><numericDomain><numberType>real</numberType></numericDomain></ratio></measurementScale></attribute><attribute><attributeName>zn_ppm</attributeName><attributeDefinition>zinc</attributeDefinition><measurementScale><ratio><unit><customUnit>milligramsPerKilogram</customUnit></unit><numericDomain><numberType>real</numberType></numericDomain></ratio></measurementScale></attribute><attribute><attributeName>s_ppm</attributeName><attributeDefinition>sulfur</attributeDefinition><measurementScale><ratio><unit><customUnit>milligramsPerKilogram</customUnit></unit><numericDomain><numberType>real</numberType></numericDomain></ratio></measurementScale></attribute><attribute><attributeName>b_ppm</attributeName><attributeDefinition>boron</attributeDefinition><measurementScale><ratio><unit><customUnit>milligramsPerKilogram</customUnit></unit><numericDomain><numberType>real</numberType></numericDomain></ratio></measurementScale></attribute><attribute><attributeName>lab</attributeName><attributeDefinition>the lab that performed the analysis</attributeDefinition><measurementScale><nominal><nonNumericDomain><textDomain><definition>the lab that performed the analysis</definition></textDomain></nonNumericDomain></nominal></measurementScale></attribute><attribute><attributeName>year</attributeName><attributeDefinition>sampling year</attributeDefinition><measurementScale><dateTime><formatString>YYYY-MM-DD</formatString><dateTimePrecision>1</dateTimePrecision><dateTimeDomain><bounds><minimum exclusive="true">1987-4-18</minimum></bounds></dateTimeDomain></dateTime></measurementScale></attribute></attributeList></dataTable></dataset><additionalMetadata><metadata><stmml:unitList xmlns:stmml="http://www.xml-cml.org/schema/stmml-1.1" xmlns="http://www.xml-cml.org/schema/stmml" xsi:schemaLocation="http://www.xml-cml.org/schema/stmml-1.1 http://nis.lternet.edu/schemas/EML/eml-2.1.0/stmml.xsd"><stmml:unit id="milliEquivalentsPerHundredGram" name="milliEquivalentsPerHundredGram"/><stmml:unit id="milligramsPerGram" name="milligramsPerGram"/><stmml:unit id="milligramsPerKilogram" name="milligramsPerKilogram"/><stmml:unit id="gramsPerHectogram" name="gramsPerHectogram"/></stmml:unitList></metadata></additionalMetadata></eml:eml>